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Non-covalent bonding interactions between tetraphenyborate anions and paraquat and diquat dications

Biomedical Sciences Research Institute Computer Science Research Institute Environmental Sciences Research Institute Nanotechnology & Advanced Materials Research Institute

Moody, GJ, Owusu, Richard, Slawin, AMZ, Spencer, N and Stoddart, JF (1987) Non-covalent bonding interactions between tetraphenyborate anions and paraquat and diquat dications. Angewandte Chemie International Edition in English, 29 (9). pp. 890-892. [Journal article]

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URL: http://www3.interscience.wiley.com/journal/106586264/abstract

DOI: 10.1002/anie.198708901

Abstract

A ternary complex - in solution and in the crystal - with - charge transfer interactions is formed be the dication paraquat (MeNC5H4C5H4NMe) and two tetraphenylborate anions. This involves face-to-face and face-to-edge interactions between pyridinium rings and phenyl rings. Scarcely more than a methyl group of the flat paraquat is discernable in the illustration on the right.

Item Type:Journal article
Faculties and Schools:Faculty of Life and Health Sciences
Faculty of Life and Health Sciences > School of Biomedical Sciences
Research Institutes and Groups:Biomedical Sciences Research Institute
Biomedical Sciences Research Institute > Northern Ireland Centre for Food and Health (NICHE)
ID Code:14695
Deposited By:Dr Richard Owusu-Apenten
Deposited On:03 Aug 2010 08:49
Last Modified:28 Jan 2014 14:46

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