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Theory of cyclic voltammetry in tubular electrodes under no flow conditions

Biomedical Sciences Research Institute Computer Science Research Institute Environmental Sciences Research Institute Nanotechnology & Advanced Materials Research Institute

Thompson, M, Davis, J and Compton, RG (2006) Theory of cyclic voltammetry in tubular electrodes under no flow conditions. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 587 (1). pp. 56-59. [Journal article]

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DOI: 10.1016/j.jelechem.2005.10.014

Abstract

Numerical modelling of the concentration profile of the electroactive species within a tubular electrode under diffusion only conditions is used to simulate cyclic voltammetry experiments. Nernst conditions are assumed at the electrode surface. The simulated peak current is compared to that given by the Randles-(S) over tilde ev (e) over tilde ik formula in order to determine the conditions of electrode size and voltage sweep rate under which there is no significant deviation from the Randles-(S) over tilde ev (e) over tilde ik result. (c) 2005 Elsevier B.V. All rights reserved.

Item Type:Journal article
Faculties and Schools:Faculty of Computing & Engineering
Faculty of Computing & Engineering > School of Engineering
Research Institutes and Groups:Engineering Research Institute
Engineering Research Institute > Nanotechnology & Integrated BioEngineering Centre (NIBEC)
ID Code:14335
Deposited By:Professor James Davis
Deposited On:01 Jul 2010 09:28
Last Modified:18 Aug 2011 11:19

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